Biomass Derived N-Doped Porous Carbon Made from Reed Straw for an Enhanced Supercapacitor.

ABSTRACT: Developing advanced carbon materials by utilizing biomass waste has attracted much attention. However, porous carbon electrodes based on the electronic-double-layer-capacitor (EDLC) charge storage mechanism generally presents unsatisfactory capacitance and energy density. Herein, an N-doped carbon material (RSM-0.33-550) was prepared by directly pyrolyzing reed straw and melamine. The micro- and meso-porous structure and the rich active nitrogen functional group offered more ion transfer and faradaic capacitance. X-ray diffraction (XRD), Raman, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) measurements were used to characterize the biomass-derived carbon materials. The prepared RSM-0.33-550 possessed an N content of 6.02% and a specific surface area of 547.1 m² g^-1. Compared with the RSM-0-550 without melamine addition, the RSM-0.33-550 possessed a higher content of active nitrogen (pyridinic-N) in the carbon network, thus presenting an increased number of active sites for charge storage. As the anode for supercapacitors (SCs) in 6 M KOH, RSM-0.33-550 exhibited a capacitance of 202.8 F g^-1 at a current density of 1 A g^-1. At a higher current density of 20 A g^-1, it still retained a capacitance of 158 F g^-1. Notably, it delivered excellent stability with capacity retention of 96.3% at 20 A g^-1 after 5000 cycles. This work not only offers a new electrode material for SCs, but also gives a new insight into rationally utilizing biomass waste for energy storage.

SUBMITTER: Liao Y 

PROVIDER: S-EPMC10301256 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature