Eu(III) and Cm(III) Complexation by the Aminocarboxylates NTA, EDTA, and EGTA Studied with NMR, TRLFS, and ITC-An Improved Approach to More Robust Thermodynamics.

ABSTRACT: The complex formation of Eu(III) and Cm(III) was studied via tetradentate, hexadentate, and octadentate coordinating ligands of the aminopolycarboxylate family, viz., nitrilotriacetate (NTA^3-), ethylenediaminetetraacetate (EDTA^4-), and ethylene glycol-bis(2-aminoethyl ether)-N,N,N',N'-tetraacetate (EGTA^4-), respectively. Based on the complexones' pK_a values obtained from ¹H nuclear magnetic resonance (NMR) spectroscopic pH titration, complex formation constants were determined by means of the parallel-factor-analysis-assisted evaluation of Eu(III) and Cm(III) time-resolved laser-induced fluorescence spectroscopy (TRLFS). This was complemented by isothermal titration calorimetry (ITC), providing the en

SUBMITTER: Friedrich S 

PROVIDER: S-EPMC10304629 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature