Stabilization of propene molybdenum and tungsten half-sandwich complexes by intramolecular coordination of a thioether function.

ABSTRACT: This study reports the stabilizing effect of an intramolecularly coordinated thioether function in propene complexes of the general formula [{η⁵:κS-C₅H₄(CH₂)₂SR}M(CO)₂(η²-C₂H₃Me)][BF₄] (M = Mo, W; R = Et, Ph). They are formed by protonation of allyl analogues [{η⁵-C₅H₄(CH₂)₂SR}M(CO)₂(η³-C₃H₅)] by tetrafluoroboric acid in non-coordinating solvents. In contrast to analogues with unsubstituted Cp ligands, these propene complexes are isolable in a pure form and characterized by NMR spectroscopy. The molybdenum compounds are stable at low temperature and the propene ligand can easil

SUBMITTER: Hanzl L 

PROVIDER: S-EPMC10311468 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature