Stepwise Assembly of Quinary Multivariate Metal-Organic Frameworks via Diversified Linker Exchange and Installation.

ABSTRACT: Multivariate MOFs (MTV-MOFs) constructed from multiple components with atomistic precision hold the promise for many fascinating developments in both fundamental sciences and applications. Sequential linker installation can be an effective method to introduce different functional linkers into an MOF that contains coordinatively unsaturated metal sites. However, in many cases, these linkers must be installed according to a specific sequence and the complete synthetic flexibility and freedom is yet to be realized. Here, we rationally decreased the size of the primary ligand used in NPF-300, a Zr-MOF with scu topology (NPF = Nebraska Porous Framework), and synthesized its isostructure, NPF-320. NPF-320 exhibits optimized pocket sizes which allow for the post-synthetic installation of t

SUBMITTER: Hu Y 

PROVIDER: S-EPMC10311524 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature