Graphene-confined ultrafast radiant heating for high-loading subnanometer metal cluster catalysts

ABSTRACT: ABSTRACT Thermally activated ultrafast diffusion, collision and combination of metal atoms comprise the fundamental processes of synthesizing burgeoning subnanometer metal clusters for diverse applications. However, so far, no method has allowed the kinetically controllable synthesis of subnanometer metal clusters without compromising metal loading. Herein, we have developed, for the first time, a graphene-confined ultrafast radiant heating (GCURH) method for the synthesis of high-loading metal cluster catalysts in microseconds, where the impermeable and flexible graphene acts as a diffusion-constrained nanoreactor for high-temperature reactions. Originating from graphene-mediated ultrafast and efficient laser-to-thermal conversion, the GCURH method is capable of providing a record-high he

SUBMITTER:  

PROVIDER: S-EPMC10317146 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature