Bright near-infrared circularly polarized electrochemiluminescence from Au₉Ag₄ nanoclusters.

ABSTRACT: Metal nanoclusters are excellent electrochemiluminescent luminophores owing to their rich electrochemical and optical properties. However, the optical activity of their electrochemiluminescence (ECL) is unknown. Herein, we achieved, for the first time, the integration of optical activity and ECL, i.e., circularly polarized electrochemiluminescence (CPECL), in a pair of chiral Au₉Ag₄ metal nanocluster enantiomers. Chiral ligand induction and alloying were employed to endow the racemic nanoclusters with chirality and photoelectrochemical reactivity. S-Au₉Ag₄ and R-Au₉Ag₄ exhibited chirality and bright-red emission (quantum yield = 4.2%) in the ground and excited states. The enantiomers showed mirror-imaged

SUBMITTER: Jiang L 

PROVIDER: S-EPMC10321486 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature