Fine tuning of electrosynthesis pathways by modulation of the electrolyte solvation structure.

ABSTRACT: Electrosynthesis is a method of choice for designing new synthetic routes owing to its ability to selectively conduct reactions at controlled potentials, high functional group tolerance, mild conditions and sustainability when powered by renewables. When designing an electrosynthetic route, the selection of the electrolyte, which is composed of a solvent, or a mixture of solvents, and a supporting salt, is a prerequisite. The electrolyte components, generally assumed to be passive, are chosen because of their adequate electrochemical stability windows and to ensure the solubilization of the substrates. However, very recent studies point towards an active role of the electrolyte in the outcome of electrosynthetic reactions, challenging its inert character. Particular structuring of the elec

SUBMITTER: Dorchies F 

PROVIDER: S-EPMC10321496 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature