2D nanosheets of layered double perovskites: synthesis, photostable bright orange emission and photoluminescence blinking.

ABSTRACT: Lead (Pb)-free layered double perovskites (LDPs) with exciting optical properties and environmental stability have sparked attention in optoelectronics, but their high photoluminescence (PL) quantum yield and understanding of the PL blinking phenomenon at the single particle level are still elusive. Herein, we not only demonstrate a hot-injection route for the synthesis of two-dimensional (2D) ∼2-3 layer thick nanosheets (NSs) of LDP, Cs₄CdBi₂Cl₁₂ (pristine), and its partially Mn-substituted analogue [i.e., Cs₄Cd_0.6Mn_0.4Bi₂Cl₁₂ (Mn-substituted)], but also present a solvent-free mechanochemical synthesis of these samples as bulk powders. Bright and intense orange emission has been perceived for pa

SUBMITTER: Bhardwaj A 

PROVIDER: S-EPMC10321497 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature