A Polar Tetragonal Tungsten Bronze with Colossal Second-Harmonic Generation.

ABSTRACT: A polar tetragonal tungsten bronze, Pb_1.91 K_3.22 □_0.85 Li_2.96 Nb₁₀ O₃₀ (□: vacancies), has been successfully synthesized by a high temperature solid-state reaction. Single crystal and powder X-ray diffraction indicate that the structure of Pb_1.91 K_3.22 □_0.85 Li_2.96 Nb₁₀ O₃₀ crystallizing in the noncentrosymmetric (NCS) space group, P4bm, consists of 3D framework with highly distorted NbO₆ , LiO₉ , PbO₁₂ , and (Pb/K)O₁₅ polyhedra. While NCS Pb_1.91 K_3.22 □_0.85 Li_2.96 Nb₁₀ O₃₀ undergoes a reversible phase transition between polar (P4bm) and nonpolar (P4/m

SUBMITTER: Kuk Y 

PROVIDER: S-EPMC10323606 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature