Polyoxometalate-Bridged Synthesis of Superstructured Mesoporous Polymers and Their Derivatives for Sodium-Iodine Batteries.

ABSTRACT: Despite the impressive progress in mesoporous materials over past decades, for those precursors having no well-matched interactions with soft templates, there are still obstacles to be guided for mesoporous structure via soft-template strategies. Here, a polyoxometalate-assisted co-assembly route is proposed for controllable construction of superstructured mesoporous materials by introducing polyoxometalates as bifunctional bridge units, which weakens the self-nucleation tendency of the precursor through coordination interactions and simultaneously connects the template through the induced dipole-dipole interaction. By this strategy, a series of meso-structured polymers, featuring highly open radial mesopores and dendritic pore walls composed of continuous interwoven nanosheets can be faci

SUBMITTER: Zhang T 

PROVIDER: S-EPMC10323648 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature