Iodine(I) and Silver(I) Complexes Incorporating 3-Substituted Pyridines.

ABSTRACT: Building upon the first report of a 3-acetaminopyridine-based iodine(I) complex (1b) and its unexpected reactivity toward ^tBuOMe, several new 3-substituted iodine(I) complexes (2b-5b) have been synthesized. The iodine(I) complexes were synthesized from their analogous silver(I) complexes (2a-5a) via a silver(I) to iodine(I) cation exchange reaction, incorporating functionally related substituents as 3-acetaminopyridine in 1b; 3-acetylpyridine (3-Acpy; 2), 3-aminopyridine (3-NH₂py; 3), and 3-dimethylaminopyridine (3-NMe₂py; 4), as well as the strongly electron-withdrawing 3-cyanopyridine (3-CNpy; 5), to probe the possible limitations of iodine(I) complex formation. The individual properties of these rar

SUBMITTER: Rissanen K 

PROVIDER: S-EPMC10324066 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature