Reductive Hydrogenation of Sulfido-Bridged Tantalum Alkyl Complexes: A Mechanistic Insight.

ABSTRACT: Hydrogenolysis of a series of alkyl sulfido-bridged tantalum(IV) dinuclear complexes [Ta(η⁵-C₅Me₅)R(μ-S)]₂ [R = Me, nBu (1), Et, CH₂SiMe₃, C₃H₅, Ph, CH₂Ph (2), p-MeC₆H₄CH₂ (3)] has led quantitatively to the Ta(III) tetrametallic sulfide cluster [Ta(η⁵-C₅Me₅)(μ₃-S)]₄ (4) along with the corresponding alkane. Mechanistic information for the formation of the unique low-valent tetrametallic compound 4 was gathered by hydrogenation of the phenyl-substituted precursor [Ta(η⁵-C₅Me₅)Ph(μ-S)]₂, which proceeds through a stepw

SUBMITTER: Carbo JJ 

PROVIDER: S-EPMC10324320 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature