A robust ultra-microporous cationic aluminum-based metal-organic framework with a flexible tetra-carboxylate linker.

ABSTRACT: Al-based cationic metal-organic frameworks (MOFs) are uncommon. Here, we report a cationic Al-MOF, MIP-213(Al) ([Al₁₈(μ₂-OH)₂₄(OH₂)₁₂(mdip)₆]6Cl·6H₂O) constructed from flexible tetra-carboxylate ligand (5,5'-Methylenediisophthalic acid; H₄mdip). Its crystal structure was determined by the combination of three-dimensional electron diffraction (3DED) and high-resolution powder X-ray diffraction. The structure is built from infinite corner-sharing chains of AlO₄(OH)₂ and AlO₂(OH)₃(H₂O) octahedra forming an 18-membered rings honeycomb lattice, similar to that of MIL-96(Al), a scarce Al-polycarboxylate defective MOF. Despite sharing these structural simi

SUBMITTER: Nandi S 

PROVIDER: S-EPMC10326013 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature