Highly Reversible Zn Metal Anodes Enabled by Increased Nucleation Overpotential.

ABSTRACT: Dendrite formation severely compromises further development of zinc ion batteries. Increasing the nucleation overpotential plays a crucial role in achieving uniform deposition of metal ions. However, this strategy has not yet attracted enough attention from researchers to our knowledge. Here, we propose that thermodynamic nucleation overpotential of Zn deposition can be boosted through complexing agent and select sodium L-tartrate (Na-L) as example. Theoretical and experimental characterization reveals L-tartrate anion can partially replace H₂O in the solvation sheath of Zn²⁺, increasing de-solvation energy. Concurrently, the Na⁺ could absorb on the surface of Zn anode preferentially to inhibit the deposition of Zn²⁺ aggregation. In consequence,

SUBMITTER: Hu Z 

PROVIDER: S-EPMC10326211 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature