Ir⁰/graphdiyne atomic interface for selective epoxidation.

ABSTRACT: The development of catalysts that can selectively and efficiently promote the alkene epoxidation at ambient temperatures and pressures is an important promising path to renewable synthesis of various chemical products. Here we report a new type of zerovalent atom catalysts comprised of zerovalent Ir atoms highly dispersed and anchored on graphdiyne (Ir⁰/GDY) wherein the Ir⁰ is stabilized by the incomplete charge transfer effect and the confined effect of GDY natural cavity. The Ir⁰/GDY can selectively and efficiently produce styrene oxides (SO) by electro-oxidizing styrene (ST) in aqueous solutions at ambient temperatures and pressures with high conversion efficiency of ∼100%, high SO selectivity of 85.5%, and high Faradaic efficiency (FE) of 55%. Experimen

SUBMITTER: Zheng Z 

PROVIDER: S-EPMC10327882 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature