Natural deep eutectic solvent-based microextraction for mercury speciation in water samples.

ABSTRACT: A new natural deep eutectic solvent (NADES)-based analytical method for mercury speciation in water samples is presented. A NADES (i.e., decanoic acid:DL-menthol in a molar ratio of 1:2) is used as an environmentally friendly extractant for separation and preconcentration using dispersive liquid-liquid microextraction before LC-UV-Vis. Under optimal extraction conditions (i.e., NADES volume, 50 µL; sample pH, 12; volume of the complexing agent, 100 µL; extraction time, 3 min; centrifugation speed, 3000 rpm; and centrifugation time, 3 min), the limit of detection values were 0.9 µg L^-1 for the organomercurial species and 3 µg L^-1 for Hg²⁺, which had a slightly higher value. The relative standard deviation (RSD, n = 6) has been evaluated at two concentration

SUBMITTER: Ripoll L 

PROVIDER: S-EPMC10328898 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature