Kinetic and Thermodynamic Enhancement of Low-Temperature Oxygen Release from Strontium Ferrite Perovskites Modified with Ag and CeO₂.

ABSTRACT: The redox behavior of the nonstoichiometric perovskite oxide SrFeO_3-δ modified with Ag, CeO₂, and Ce was assessed for chemical looping air separation (CLAS) via thermogravimetric analysis and by cyclic release and uptake of O₂ in a packed bed reactor. The results demonstrated that the addition of ∼15 wt % Ag at the surface of SrFeO_3-δ lowers the temperature of oxygen release in N₂ by ∼60 °C (i.e., from 370 °C for bare SrFeO_3-δ to 310 °C) and more than triples the amount of oxygen released per CLAS cycle at 500 °C. Impregnation of SrFeO_3-δ with Ag increased the concentration of oxygen vacancies at equilibrium, lowering (3 - δ) under all investigated oxygen partial pressures. The addition of CeO₂ at the s

SUBMITTER: Harrison ARP 

PROVIDER: S-EPMC10331733 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature