Understanding the Oxidative Properties of Nickel Oxyhydroxide in Alcohol Oxidation Reactions.

ABSTRACT: The NiOOH electrode is commonly used in electrochemical alcohol oxidations. Yet understanding the reaction mechanism is far from trivial. In many cases, the difficulty lies in the decoupling of the overlapping influence of chemical and electrochemical factors that not only govern the reaction pathway but also the crystal structure of the in situ formed oxyhydroxide. Here, we use a different approach to understand this system: we start with synthesizing pure forms of the two oxyhydroxides, β-NiOOH and γ-NiOOH. Then, using the oxidative dehydrogenation of three typical alcohols as the model reactions, we examine the reactivity and selectivity of each oxyhydroxide. While solvent has a clear effect on the reaction rate of β-NiOOH, the observed selectivity was found to be unaffected and

SUBMITTER: Laan PCM 

PROVIDER: S-EPMC10334462 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature