Exciton dissociation in 2D layered metal-halide perovskites.

ABSTRACT: Layered 2D perovskites are making inroads as materials for photovoltaics and light emitting diodes, but their photophysics is still lively debated. Although their large exciton binding energies should hinder charge separation, significant evidence has been uncovered for an abundance of free carriers among optical excitations. Several explanations have been proposed, like exciton dissociation at grain boundaries or polaron formation, without clarifying yet if excitons form and then dissociate, or if the formation is prevented by competing relaxation processes. Here we address exciton stability in layered Ruddlesden-Popper PEA₂PbI₄ (PEA stands for phenethylammonium) both in form of thin film and single crystal, by resonant injection of cold excitons, whose dissociation

SUBMITTER: Simbula A 

PROVIDER: S-EPMC10336065 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature