Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuring η⁶-arene interactions.

ABSTRACT: Reaction of the terphenyl bis(anilide) ligand [{K(DME)₂}₂L^Ar] (L^Ar = {C₆H₄[(2,6-ⁱPr²C₆H₃)NC₆H₄]₂}^2-) with trivalent chloride "MCl₃" salts (M = Ce, U, Np) yields two distinct products; neutral L^ArM(Cl)(THF) (1^M) (M = Np, Ce), and the "-ate" complexes [K(DME)₂][(L^Ar)Np(Cl)₂] (2^Np) or ([L^ArM(Cl)₂(μ-K(X)₂)])_∞ (2^Ce, 2^U) (M = Ce, U) (X = DME or Et₂O) (2^M). Alternatively, analogous reactions with the iodide [MI₃(THF)₄] salts provide access to the neutral

SUBMITTER: Murillo J 

PROVIDER: S-EPMC10337748 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature