Order-disorder and ionic conductivity in calcium nitride-hydride.

ABSTRACT: Recently nitrogen-hydrogen compounds have successfully been applied as co-catalysts for mild conditions ammonia synthesis. Ca₂NH was shown to act as a H₂ sink during reaction, with H atoms from its lattice being incorporated into the NH₃(g) product. Thus the ionic transport and diffusion properties of the N-H co-catalyst are fundamentally important to understanding and developing such syntheses. Here we show hydride ion conduction in these materials. Two distinct calcium nitride-hydride Ca₂NH phases, prepared via different synthetic paths are found to show dramatically different properties. One phase (β) shows fast hydride ionic conduction properties (0.08 S/cm at 600 °C), on a par with the best binary ionic hydrides and 10 times higher than CaH<

SUBMITTER: Irvine GJ 

PROVIDER: S-EPMC10359262 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature