Engineering Robust Metallic Zero-Mode States in Olympicene Graphene Nanoribbons.

ABSTRACT: Metallic graphene nanoribbons (GNRs) represent a critical component in the toolbox of low-dimensional functional materials technology serving as 1D interconnects capable of both electronic and quantum information transport. The structural constraints imposed by on-surface bottom-up GNR synthesis protocols along with the limited control over orientation and sequence of asymmetric monomer building blocks during the radical step-growth polymerization have plagued the design and assembly of metallic GNRs. Here, we report the regioregular synthesis of GNRs hosting robust metallic states by embedding a symmetric zero-mode (ZM) superlattice along the backbone of a GNR. Tight-binding electronic structure models predict a strong nearest-neighbor electron hopping interaction between adjacent ZM stat

SUBMITTER: McCurdy RD 

PROVIDER: S-EPMC10360063 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature