Influence of halogen elements in organic salts on n-type doping of CNT yarn for thermoelectric applications.

ABSTRACT: Doping control of carbon nanotube (CNT) is crucial for thermoelectric (TE) application to maximize the power conversion efficiency. Despite the recent achievement of good air stability by organic salts for n-type carrier doping, their doping mechanism has not been systematically investigated so far. Here, we demonstrate doping of CNT yarn using ammonium salts with different halogen elements (tetra-butylammonium salts, TBAX where X = Cl, Br, or I) through the dipping technique. By changing the halogen element, we specifically investigated the halogen effect in the n-type doping process of CNT. The introduction of each material into the CNT yarn and its doping reaction were then studied by energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. Halogen element was found to

SUBMITTER: Heriyanto ADM 

PROVIDER: S-EPMC10363687 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature