Giant uniaxial negative thermal expansion in FeZr₂ alloy over a wide temperature range.

ABSTRACT: Negative thermal expansion (NTE) alloys possess great practical merit as thermal offsets for positive thermal expansion due to its metallic properties. However, achieving a large NTE with a wide temperature range remains a great challenge. Herein, a metallic framework-like material FeZr₂ is found to exhibit a giant uniaxial (1D) NTE with a wide temperature range (93-1078 K, [Formula: see text]). Such uniaxial NTE is the strongest in all metal-based NTE materials. The direct experimental evidence and DFT calculations reveal that the origin of giant NTE is the couple with phonons, flexible framework-like structure, and soft bonds. Interestingly, the present metallic FeZr₂ excites giant 1D NTE mainly driven by high-frequency optical branches. It is unlike the NTE in trad

SUBMITTER: Xu M 

PROVIDER: S-EPMC10366141 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature