Cupric coordination compounds with multiple anions: a promising strategy for the regulation of energetic materials.

ABSTRACT: To seek new high energetic materials, N-methylene-C-bridged nitrogen-rich heterocycle 1-((4,5-diamino-4H-1,2,4-triazol-3-yl)methyl)-1H-1,2,4-triazol-3,5-diamine (DATMTDA) (2) was first synthesized, and two copper coordination compounds ([Cu₁₂(OH)₄(ClO₄)₄(H₂O)₄(DATMTDA)₁₂](ClO₄)₁₆·12H₂O (3) and [Cu₃(OH)(ClO₄)(DATMTDA)₃](ClO₄)₃(NO₃) (4)) based on 2 were formed by introducing different anions. These compounds were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction analysis. The crystal structures of compounds 3 and 4 are similar and crystallize in monoclinic systems w

SUBMITTER: Xia LH 

PROVIDER: S-EPMC10368156 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature