Surface Reconstruction and Passivation of BiVO₄ Photoanodes Depending on the "Structure Breaker" Cs.

ABSTRACT: Monoclinic BiVO₄ is one of the most promising photoanode materials for solar water splitting. The photoelectrochemical performance of a BiVO₄ photoanode could be significantly influenced by the noncovalent interactions of redox-inert metal cations at the photoanode-electrolyte interfaces, but this point has not been well investigated. In this work, we studied the Cs⁺-dependent surface reconstruction and passivation of BiVO₄ photoanodes. Owing to the "structure breaker" nature of Cs⁺, the Cs⁺ at the BiVO₄ photoanode-electrolyte interfaces participated in BiVO₄ surface photocorrosion to form a Cs⁺-doped bismuth vanadium oxide amorphous thin layer, which inhibited the continuous photocorrosion o

SUBMITTER: Tao C 

PROVIDER: S-EPMC10369408 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature