Dataset Information

Electronic Tuning of CO₂ Interaction by Oriented Coordination of N-Rich Auxiliary in Porphyrin Metal-Organic Frameworks for Light-Assisted CO₂ Electroreduction.

ABSTRACT: The efficient CO₂ electroreduction into high-value products largely relies on the CO₂ adsorption/activation or electron-transfer of electrocatalysts, thus site-specific functionalization methods that enable boosted related interactions of electrocatalysts are much desired. Here, an oriented coordination strategy is reported to introduce N-rich auxiliary (i.e., hexamethylenetetramine, HMTA) into metalloporphyrin metal organic frameworks (MOFs) to synthesize a series of site-specific functionalized electrocatalysts (HMTA@MOF-545-M, M = Fe, Co, and Ni) and they are successfully applied in light-assisted CO₂ electroreduction. Noteworthy, thus-obtained HMTA@MOF-545-Co presents approximately two times enhanced CO₂ adsorption-enthalpy and electrochemica

SUBMITTER: Xin Z

PROVIDER: S-EPMC10375083 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature

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Dataset Information

Electronic Tuning of CO₂ Interaction by Oriented Coordination of N-Rich Auxiliary in Porphyrin Metal-Organic Frameworks for Light-Assisted CO₂ Electroreduction.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Electronic Tuning of CO2 Interaction by Oriented Coordination of N-Rich Auxiliary in Porphyrin Metal-Organic Frameworks for Light-Assisted CO2 Electroreduction.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Electronic Tuning of CO₂ Interaction by Oriented Coordination of N-Rich Auxiliary in Porphyrin Metal-Organic Frameworks for Light-Assisted CO₂ Electroreduction.