Pd-Based Nano-Catalysts Promote Biomass Lignin Conversion into Value-Added Chemicals.

ABSTRACT: Lignin, as a structurally complex biomaterial, offers a valuable resource for the production of aromatic chemicals; however, its selective conversion into desired products remains a challenging task. In this study, we prepared three types of Pd-based nano-catalysts and explored their application in the depolymerization of alkali lignin, under both H₂-free (hydrogen transfer) conditions and H₂ atmosphere conditions. The materials were well characterized with TEM, XRD, and XPS and others, and the electronic interactions among Pd, Ni, and P were analyzed. The results of lignin depolymerization experiments revealed that the ternary Pd-Ni-P catalyst exhibited remarkable performance and guaiacols could be produced under H₂ atmosphere conditions in 14.2 wt.% yield

SUBMITTER: Zhao M 

PROVIDER: S-EPMC10384994 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature