Semi-Interpenetrating Network Anion Exchange Membranes by Thiol-Ene Coupling Reaction for Alkaline Fuel Cells and Water Electrolyzers.

ABSTRACT: In this work, a thiol-ene coupling reaction was employed to prepare the semi-interpenetrating polymer network AEMs. The obtained QP-1/2 membrane exhibits high hydroxide conductivity (162.5 mS cm^-1 at 80 °C) with a relatively lower swelling ratio, demonstrating its mechanical strength of 42 MPa. This membrane is noteworthy for its improved alkaline stability, as the semi-interpenetrating network effectively limits the attack of hydroxide. Even after being treated in 2 M NaOH at 80 °C for 600 h, 82.5% of the hydroxide conductivity is maintained. The H₂/O₂ fuel cell with QP-1/2 membrane displays a peak power density of 521 mW cm^-2. Alkaline water electrolyzers based on QP-1/2 membrane demonstrated a current density of 1460 mA cm^-2 at a ce

SUBMITTER: Jin Z 

PROVIDER: S-EPMC10385286 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature