Reassigning the Pressure-Induced Phase Transitions of Methylammonium Lead Bromide Perovskite.

ABSTRACT: The high-pressure crystal structure evolution of CH₃NH₃PbBr₃ (MAPbBr₃) perovskite has been investigated by single-crystal X-ray diffraction and synchrotron-based powder X-ray diffraction. Single-crystal X-ray diffraction reveals that the crystal structure of MAPbBr₃ undergoes two phase transitions following the space-group sequence: Pm3̅m → Im3̅ → Pmn2₁, unveiling the occurrence of a nonpolar/polar transition (Im3̅ → Pmn2₁). The transitions take place at around 0.8 and 1.8 GPa, respectively. This result contradicts the previously reported phase transition sequence: Pm3̅m → Im3̅ →Pnma. In this work, the crystal structures of each of the th

SUBMITTER: Liang A 

PROVIDER: S-EPMC10388295 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature