Nucleation and Growth of Bipyramidal Yb:LiYF₄ Nanocrystals-Growing Up in a Hot Environment.

ABSTRACT: Lanthanide-doped LiYF₄ (Ln:YLF) is commonly used for a broad variety of optical applications, such as lasing, photon upconversion and optical refrigeration. When synthesized as nanocrystals (NCs), this material is also of interest for biological applications and fundamental physical studies. Until now, it was unclear how Ln:YLF NCs grow from their ionic precursors into tetragonal NCs with a well-defined, bipyramidal shape and uniform dopant distribution. Here, we study the nucleation and growth of ytterbium-doped LiYF₄ (Yb:YLF), as a template for general Ln:YLF NC syntheses. We show that the formation of bipyramidal Yb:YLF NCs is a multistep process starting with the formation of amorphous Yb:YLF spheres. Over time, these spheres grow via Ostwald ripening and crystall

SUBMITTER: Mulder JT 

PROVIDER: S-EPMC10389792 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature