Observation of induction period and oxygenated intermediates in methane oxidation over Pt catalyst.

ABSTRACT: Selective oxidation of methane is one of the most attractive routes for methane to chemicals. However, mechanistic understanding and avoiding over-oxidation have great challenges because of its very rapid reaction rate. Herein, a capillary micro-reaction system was introduced to monitor the initial stage of methane oxidation over platinum. For the first time, an induction period is observed, during which oxygenated intermediates, such as methanol, acetone, methyl methoxy acetate, etc., are detected. Induction period can be shortened by methane pretreatment at 600°C, which generates highly active species containing unsaturated bonds. Combined these findings and observations of in situ characterizations, the evolution route of methane oxidation over Pt is prosed, i.e., the reaction st

SUBMITTER: Yang K 

PROVIDER: S-EPMC10391729 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature