Synthesis and Characterization of Octacyano-Fe-Phthalocyanine.

ABSTRACT: Octacyano-metal-phthalocyanine MPc(CN)₈ is a promising n-type stable organic semiconductor material with eight cyano groups, including a strong electron-withdrawing group at its molecular terminals. However, a thorough investigation of MPc(CN)₈ has not yet been conducted. Therefore, we synthesized FePc(CN)₈ and investigated its crystal structure, chemical and electronic states, electrical properties, photocatalytic activity, and magnetic properties. In this paper, we discuss the various properties of MPc(CN)₈ in comparison with those of FePc. X-ray diffraction measurements indicated that the crystal structure of FePc(CN)₈ was strongly influenced by the cyano groups and differed from the α- and β-forms of FePc. The space group P4

SUBMITTER: Isobe M 

PROVIDER: S-EPMC10399171 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature