Flexible All-Inorganic Perovskite Photodetector with a Combined Soft-Hard Layer Produced by Ligand Cross-Linking.

ABSTRACT: Although perovskite nanocrystals have attracted considerable interests as emerging semiconductors in optoelectronic devices, design and fabrication of a deformable structure with high stability and flexibility while meeting the charge transport requirements remain a huge challenge. Herein, a combined soft-hard strategy is demonstrated to fabricate intrinsically flexible all-inorganic perovskite layers for photodetection via ligand cross-linking. Perfluorodecyltrichlorosilane (FDTS) is employed as the capping ligand and passivating agent bound to the CsPbBr₃ surface via Pb-F and Br-F interactions. The SiCl head groups of FDTS are hydrolyzed to produce SiOH groups which subsequently condense to form the SiOSi network. The CsPbBr₃ @FDTS nanocrystals (NCs) are monodis

SUBMITTER: Shi T 

PROVIDER: S-EPMC10401168 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature