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Size-dependent vitrification in metallic glasses.

ABSTRACT: Reducing the sample size can profoundly impact properties of bulk metallic glasses. Here, we systematically reduce the length scale of Au and Pt-based metallic glasses and study their vitrification behavior and atomic mobility. For this purpose, we exploit fast scanning calorimetry (FSC) allowing to study glassy dynamics in an exceptionally wide range of cooling rates and frequencies. We show that the main α relaxation process remains size independent and bulk-like. In contrast, we observe pronounced size dependent vitrification kinetics in micrometer-sized glasses, which is more evident for the smallest samples and at low cooling rates, resulting in more than 40 K decrease in fictive temperature, T_f, with respect to the bulk. We discuss the deep implications on how this outcome can be used to convey glasses to low energy states.

SUBMITTER: Di Lisio V

PROVIDER: S-EPMC10403508 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature

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Size-dependent vitrification in metallic glasses.

Di Lisio Valerio V Gallino Isabella I Riegler Sascha Sebastian SS Frey Maximilian M Neuber Nico N Kumar Golden G Schroers Jan J Busch Ralf R Cangialosi Daniele D

Nature communications 20230804 1

Reducing the sample size can profoundly impact properties of bulk metallic glasses. Here, we systematically reduce the length scale of Au and Pt-based metallic glasses and study their vitrification behavior and atomic mobility. For this purpose, we exploit fast scanning calorimetry (FSC) allowing to study glassy dynamics in an exceptionally wide range of cooling rates and frequencies. We show that the main α relaxation process remains size independent and bulk-like. In contrast, we observe prono ...[more]

PMID: 37542023

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