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XRD, FTIR and ultrasonic investigations of cadmium lead bismuthate glasses.

ABSTRACT: Cadmium lead bismuthate glasses in the system xCdO-(1-x)[0.5PbO + 0.5Bi₂O₃](40 mol% ≤ x ≤ 90 mol%) were successfully prepared by melt-quenching method. The structural and elastic properties have been investigated using XRD, FTIR and ultrasonic pulse-echo techniques. The XRD patterns confirmed the amorphous nature of the samples prepared. Density and ultrasonic velocity data were used to evaluate various elastic properties. Addition of CdO gave rise to decreased density and molar volume and increased elastic moduli, micro-hardness, and Debye temperature. The FTIR analysis revealed that increasing CdO content enhances the BiO₆ octahedral sites at the expense of the BiO₃ and PbO₄ units. This results in the formation of Pb-O-Bi(6) and Bi(3)-O-Bi(6) linkages in the glass network, which stiffen the structure and improve the elastic properties. A correlation between elastic and compositional parameters was achieved on the basis of theories and approaches in the field.

SUBMITTER: Abd El-Moneim A

PROVIDER: S-EPMC10406924 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature

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XRD, FTIR and ultrasonic investigations of cadmium lead bismuthate glasses.

Abd El-Moneim Amin A Azooz M A MA Hashem Hassan A HA Fayad A M AM Elwan R L RL

Scientific reports 20230807 1

Cadmium lead bismuthate glasses in the system xCdO-(1-x)[0.5PbO + 0.5Bi<sub>2</sub>O<sub>3</sub>](40 mol% ≤ x ≤ 90 mol%) were successfully prepared by melt-quenching method. The structural and elastic properties have been investigated using XRD, FTIR and ultrasonic pulse-echo techniques. The XRD patterns confirmed the amorphous nature of the samples prepared. Density and ultrasonic velocity data were used to evaluate various elastic properties. Addition of CdO gave rise to decreased density and ...[more]

PMID: 37550313

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Project description:Research on the composition and structure of coal is the most important and complex basic research in the coal chemistry field. Various methods have been used to study the structure of coal from different perspectives. However, due to the complexity of coal and the limitations of research methods, research on the macromolecular structure of coal still lacks systematicness. Huainan coalfield is located in eastern China and is the largest coal production and processing base in the region. In this study, conventional proximate analysis and ultimate analysis, as well as advanced instrumental analysis methods, such as Fourier transform infrared spectroscopy (FITR), X-ray diffraction (XRD), 13C-CP/MAS NMR, and other methods (SEM and AFM), were used to analyze the molecular structure of Huainan coal (HNC) and the distribution characteristics of oxygen in different oxygen-containing functional groups (OCFGs) in an in-depth manner. On the basis of SEM observation, it could be concluded that the high-resolution morphology of HNC's surface contains pores and fractures of different sizes. The loose arrangement pattern of HNC's molecular structure could be seen from 3D AFM images. The XRD patterns show that the condensation degree of HNC's aromatic ring is low, and the orientation degree of carbon network lamellae is poor. The calculated ratio of the diameter of aromatic ring lamellae to their stacking height (La/Lc = 1.05) and the effective stacking number of aromatic nuclei (Nave = 7.3) show that the molecular space structure of HNC is a cube formed of seven stacked aromatic lamellae. The FTIR spectra fitting results reveal that the aliphatic chains in HNC's molecular structure are mainly methyne and methylene. Oxygen is mainly -O-, followed by -C=O, and contains a small amount of -OH, the ratio of which is about 8:1:2. The molar fraction of binding elements has the approximate molecular structure C100H76O9N of organic matter in HNC. The results of the 13C NMR experiments show that the form of aromatic carbon atoms in HNC's structure (the average structural size X_b of aromatic nucleus = 0.16) is mainly naphthalene with a condensation degree of 2, and the rest are aromatic rings composed of benzene rings and heteroatoms. In addition, HNC is relatively rich in ≡CH and -CH2- structures.

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XRD, FTIR and ultrasonic investigations of cadmium lead bismuthate glasses.

Publications

XRD, FTIR and ultrasonic investigations of cadmium lead bismuthate glasses.

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