Dataset Information

Formation of Irida-β-ketoimines and PCN^amine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H₃N-BH₃.

ABSTRACT: Aliphatic diamines [(H₂N(CH₂)_nNHR) (a-d) n = 2: R = H (a), R = CH₃ (b), R = C₂H₅ (c), n = 3, R = H (d) or rac-2-(aminomethyl)piperidine (e)] react with [IrH(Cl){(PPh₂(o-C₆H₄CO))₂H}] in THF to afford ketoimine complexes [IrH(Cl){(PPh₂(o-C₆H₄CO))(PPh₂(o-C₆H₄CN(CH₂)_nNHR))H}] (2a-2d) or [IrH(Cl){(PPh₂(o-C₆H₄CO))(PPh₂(o-C₆H₄CNCH₂(C₅H₉NH)))H}] (2e), containing a bridging N-

SUBMITTER: Bustos I

PROVIDER: S-EPMC10407880 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature

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Dataset Information

Formation of Irida-β-ketoimines and PCN^amine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H₃N-BH₃.

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Dataset Information

Formation of Irida-β-ketoimines and PCNamine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H3N-BH3.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Formation of Irida-β-ketoimines and PCN^amine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H₃N-BH₃.