Interfacial Effects in Conductivity Measurements of Block Copolymer Electrolytes.

ABSTRACT: The ionic conductivity in lamellar block copolymer electrolytes is often anisotropic, where the in-plane conductivity exceeds the through-plane conductivity by up to an order of magnitude. In a prior work, we showed significant anisotropy in the ionic conductivity of a lamellar block copolymer based on polystyrene (PS) and a polymer ionic liquid (PIL), and we proposed that the through-film ionic conductivity was depressed by layering of lamellar domains near the electrode surface. In the present work, we first tested that conclusion by measuring the through-plane ionic conductivity of two model PIL-based systems having controlled interfacial profiles using impedance spectroscopy. The measurements were not sensitive to changes in interfacial composition or structure, so anisotropy in the io

SUBMITTER: Coote JP 

PROVIDER: S-EPMC10416321 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature