Oxygen Vacancy and Interface Effect Adjusted Hollow Dodecahedrons for Efficient Oxygen Evolution Reaction.

ABSTRACT: Metal-organic frameworks (MOFs) with special morphologies provide the geometric morphology and composition basis for the construction of platforms with excellent catalytic activity. In this work, cobalt-cerium composite oxide hollow dodecahedrons (Co/Cex-COHDs) with controllable morphology and tunable composition are successfully prepared via a high-temperature pyrolysis strategy using Co/Ce-MOFs as self-sacrificial templates. The construction of the hollow structure can expose a larger surface area to provide abundant active sites and pores to facilitate the diffusion of substances. The formation and optimization of phase interface between Co₃O₄ and CeO₂ regulate the electronic structure of the catalytic site and form a fast channel favorable to electron t

SUBMITTER: Wang H 

PROVIDER: S-EPMC10419998 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature