1,2,3-Triazoles: Controlled Switches in Logic Gate Applications.

ABSTRACT: A 1,2,3-triazole-based chemosensor is used for selective switching in logic gate operations through colorimetric and fluorometric response mechanisms. The molecular probe synthesized via "click chemistry" resulted in a non-fluorescent 1,4-diaryl-1,2,3-triazole with a phenol moiety (PTP). However, upon sensing fluoride, it TURNS ON the molecule's fluorescence. The TURN-OFF order occurs through fluorescence quenching of the sensor when metal ions, e.g., Cu²⁺, and Zn²⁺, are added to the PTP-fluoride ensemble. A detailed characterization using Nuclear Magnetic Resonance (NMR) spectroscopy in a sequential titration study substantiated the photophysical characteristics of PTP through UV-Vis absorption and fluorescence profiles. A combination of fluoresc

SUBMITTER: Ghosh D 

PROVIDER: S-EPMC10422406 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature