Ontology highlight
ABSTRACT:
SUBMITTER: Li XX
PROVIDER: S-EPMC10439156 | biostudies-literature | 2023 Aug
REPOSITORIES: biostudies-literature
Li Xue-Xin XX Li Cai-Hong CH Hou Ming-Jun MJ Zhu Bo B Chen Wei-Chao WC Sun Chun-Yi CY Yuan Ye Y Guan Wei W Qin Chao C Shao Kui-Zhan KZ Wang Xin-Long XL Su Zhong-Min ZM
Nature communications 20230818 1
Precise synthesis of polyoxometalates (POMs) is important for the fundamental understanding of the relationship between the structure and function of each building motif. However, it is a great challenge to realize the atomic-level tailoring of specific sites in POMs without altering the major framework. Herein, we report the case of Ce-mediated molecular tailoring on gigantic {Mo<sub>132</sub>}, which has a closed structural motif involving a never seen {Mo<sub>110</sub>} decamer. Such capped w ...[more]