Crystal structure of bis­{S-octyl-3-[(thio­phen-2-yl)methyl­idene]di­thio­carbazato-κ2N3,S}nickel(II)

ABSTRACT: The mononuclear nickel(II) complex is bis-chelated by di­thio­carbazato ligands bearing a thienyl ring and an n-octyl alkyl chain. In the title complex, [Ni(C14H21N2S3)2], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The mol­ecules stack at a distance of 3.623 (2) Å along the b-axis direction.

SUBMITTER: Khan S 

PROVIDER: S-EPMC10439407 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature