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Crystal structure and luminescence spectrum of a one-dimensional nickel(II) coordination polymer incorporating 1,4-bis-[(2-methyl-imidazol-1-yl)meth-yl]benzene and adamantane-1,3-di-carboxyl-ate co-ligands.

ABSTRACT: An NiII coordination polymer, namely, poly[(μ2-adamantane-1,3-di-carboxyl-ato-κ4 O 1,O 1':O 3,O 3')[μ2-1,4-bis-(2-methyl-imidazol-1-ylmeth-yl)benzene-κ2 N 3:N 3']nickel(II)], [Ni(C12H14O4)(C16H18N4)]n or [Ni(adc)(bmib)]n, (I) [adc = adamantane-1,3-di-carboxyl-ate, C12H14O4 2- and bmib = 1,4-bis-(2-methyl-imidazol-1-ylmeth-yl)benzene, C16H18N4] was synthesized and characterized. It exhibits a one-dimensional extended structure built up from alternating [Ni2(bmib)2] 26-membered rings and [Ni2(adc)2] 16-membered rings. The nickel atom lies on a crystallographic twofold axis and both ligands are completed by mirror symmetry. The solid-state luminescence spectra of (I) and the bmib ligand show strong emissions at 442 and 410 nm, respectively.

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC10439420 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature

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Crystal structure and luminescence spectrum of a one-dimensional nickel(II) coordination polymer incorporating 1,4-bis-[(2-methyl-imidazol-1-yl)meth-yl]benzene and adamantane-1,3-di-carboxyl-ate co-ligands.

Zhang Yong Y   Qin Hongni H   Wu Bing B  

Acta crystallographica. Section E, Crystallographic communications 20230714 Pt 8

An Ni<sup>II</sup> coordination polymer, namely, poly[(μ<sub>2</sub>-adamantane-1,3-di-carboxyl-ato-κ<sup>4</sup> <i>O</i> <sup>1</sup>,<i>O</i> <sup>1'</sup>:<i>O</i> <sup>3</sup>,<i>O</i> <sup>3'</sup>)[μ<sub>2</sub>-1,4-bis-(2-methyl-imidazol-1-ylmeth-yl)benzene-κ<sup>2</sup> <i>N</i> <sup>3</sup>:<i>N</i> <sup>3'</sup>]nickel(II)], [Ni(C<sub>12</sub>H<sub>14</sub>O<sub>4</sub>)(C<sub>16</sub>H<sub>18</sub>N<sub>4</sub>)]<sub><i>n</i></sub> or [Ni(adc)(bmib)]<sub><i>n</i></sub>, (I) [adc = ad  ...[more]

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