Crystal structure of 5-(β-d-gluco­pyran­osyl­thio)-N-(4-methyl­phen­yl)-1,3,4-thia­diazol-2-amine

ABSTRACT: In the title compound, the angle between the tolyl and thia­diazole rings is 9.2 (1)°. The hydrogen bonding is a combination of a ribbon involving hydrogen bonds of the sugar residues, and a layer based on N—H⋯O and O—H⋯N hydrogen bonds. In the structure of the title compound, C15H19N3O5S2, the bond lengths at the linking sulfur atom are significantly different [1.7473 (17) and 1.811 (2) Å], and the angle at the exocyclic nitro­gen atom is wide at 128.45 (18)°. The inter­planar angle between the tolyl and thia­diazole rings is 9.2 (1)°. The complex hydrogen-bonding pattern, involving five donors and five acceptors, can be broken down into a one-dimensional ribbon parallel to the b axis, involving hydrogen bonds of the sugar residues only, and a two-dimensional layer structure parallel to t

SUBMITTER: Abu-Zaied M 

PROVIDER: S-EPMC10439424 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature