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Crystal structure of Ag₃Dy₂(NO₃)₉ and qu-anti-tative comparison to isotypic compounds.

ABSTRACT: Single crystals of Ag₃Dy₂(NO₃)₉ (tris-ilver didysprosium nona-nitrate) were obtained from a mixture of AgNO₃ and Dy(NO₃)₃·5 H₂O. The new compound crystallizes in space group P4₁32 (No. 213) with a = 13.2004 (4) Å, V = 2300.2 (2) Å³, Z = 4. The Ag and Dy cations are coordinated by five and six bidentate nitrate anions, respectively. Ag₃Dy₂(NO₃)₉ is isostructural to several compounds that include alkali metals or ammonium and lanthanide cations, but silver and dysprosium are included for the first time and feature the smallest ion radii observed for this structure type to date. Crystal structures of isotypic compounds are compared.

SUBMITTER: Klein W

PROVIDER: S-EPMC10439438 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of Ag3Dy2(NO3)9 and qu-anti-tative comparison to isotypic compounds.

Klein Wilhelm W

Acta crystallographica. Section E, Crystallographic communications 20230602 Pt 7

Single crystals of Ag3Dy2(NO3)9 (tris-ilver didysprosium nona-nitrate) were obtained from a mixture of AgNO3 and Dy(NO3)3·5 H2O. The new compound crystallizes in space group P4132 (No. 213) with a = 13.2004 (4) Å, V = 2300.2 (2) Å3, Z = 4. The Ag and Dy cations are coordinated by five and six bidentate nitrate anions, respectively. Ag3Dy2 ...[more]

PMID: 37601568

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