Preparation of spiroborate supramolecular and peapod polymers containing a photoluminescent ruthenium(ii) complex† † Electronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d3ra03940d

ABSTRACT: The immobilization of functional metal complexes onto polymer supports remains one of the most important research areas. In this study, we prepared spiroborate supramolecular and peapod polymers containing a cationic photoluminescent ruthenium(ii) complex. The supramolecular polymer was obtained by mixing spiroborate cyclic trimer bearing homoallyl group and a ruthenium(ii) tris(bipyridyl) complex, and was further converted into the corresponding peapod polymer by olefin metathesis polymerization. The structure of these polymers was determined by 1H NMR, dynamic light scattering, inductively coupled plasma-atomic emission spectroscopy, energy dispersive X-ray analyses, and atomic force microscopy. The absorption and emission behaviors of the ruthenium(ii) complex were almost the same for t

SUBMITTER: Matsumoto W 

PROVIDER: S-EPMC10445220 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature