Polyamidoamine Dendrimers Functionalized Water-Stable Metal-Organic Frameworks for Sensitive Fluorescent Detection of Heavy Metal Ions in Aqueous Solution.

ABSTRACT: In this work, polyamidoamine (PAMAM)-functionalized water-stable Al-based metal-organic frameworks (MIL-53(Al)-NH₂) were proposed with enhanced fluorescence intensity, and used for the sensitive detection of heavy metal ions in aqueous solution. The size and morphology of MIL-53(Al)-NH₂ were effectively optimized by regulating the component of the reaction solvents. PAMAM dendrimers were subsequently grafted onto the surface with glutaraldehyde as a cross-linking agent. It was found that the size and morphology of MIL-53(Al)-NH₂ have great influence on their fluorescence properties, and PAMAM grafting could distinctly further improve their fluorescence intensity. With higher fluorescence intensity, the PAMAM-grafted MIL-53(Al)-NH₂ showed good lin

SUBMITTER: Guo D 

PROVIDER: S-EPMC10458630 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature