Three Iodoargentate-Based Hybrids Decorated by Metal Complexes: Structures, Optical/Photoelectric Properties and Theoretical Studies.

ABSTRACT: So far, the development of new iodoargentate-based hybrids, especially those compounds with metal complex cations, and the understanding of their structure-activity relationships have been of vital importance but full of challenges. Herein, using the in-situ-generated metal complex cations as structural directing agents, three new iodoargentate-based hybrids, namely, [Co(phen)₃]Ag₂PbI₆ (phen = 1,10-phenanthroline; 1), [Ni(5,5-dmpy)₃]Ag₇I₉·CH₃CN (5,5-dmpy = 5,5-dimethyl-2,2-bipyridine; 2) and [Co(5,5-dmpy)₃]Ag₅I₈ (3), have been solvothermally prepared and then structurally characterized. Compound 1 represents one new heterometallic Ag-Pb-I compound charac

SUBMITTER: Liu M 

PROVIDER: S-EPMC10458760 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature