Group 10 Metal Allyl Amidinates: A Family of Readily Accessible and Stable Molecular Precursors to Generate Supported Nanoparticles.

ABSTRACT: The synthesis of well-defined materials as model systems for catalysis and related fields is an important pillar in the understanding of catalytic processes at a molecular level. Various approaches employing organometallic precursors have been developed and established to make monodispersed supported nanoparticles, nanocrystals, and films. Using rational design principles, a new family of precursors based on group 10 metals suitable for the generation of small and monodispersed nanoparticles on metal oxides has been developed. Particle formation on SiO₂ and Al₂O₃ supports is demonstrated, as well as the potential in the synthesis of bimetallic catalyst materials, exemplified by a PdGa/SiO₂ system capable of hydrogenation of CO₂ to meth

SUBMITTER: Ehinger C 

PROVIDER: S-EPMC10466329 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature