Poly[[aqua-[μ₂-1,3-bis-(pyridin-4-yl)urea-κ²N⁴:N^4']bis-(μ₃-5-tert-butyl-isophthalato-κ³O¹:O^1':O³)dizinc(II)] trihydrate], a double-strand coordination polymer.

ABSTRACT: In the title compound, {[Zn₂(C₁₂H₁₂O₄)₂(C₁₁H₁₀N₄O)(H₂O)]·3H₂O}_n, monoperiodic coordination polymer double strands are held into the triperiodic crystal structure by means of N-H⋯O hydrogen-bonding patterns between the amide groups of the 1,3-di(pyridin-4-yl)urea ligands and unligated O atoms belonging to 5-tert-butyl-isophthalate ligands. One of the Zn atoms displays a tetra-hedral coordination environment, while the other Zn atom adopts a five-coordinate geometry inter-mediate between square pyramidal and trigonal bipyramidal. Additionally, O-H⋯O hydrogen-bonding patterns involving the water mol-ecules of crystallization serve as a structure-stabilizing el

SUBMITTER: Jia J 

PROVIDER: S-EPMC10483537 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature